DFT modeling of the effect of magnesium dichloride on the catalytic activity of post-titanocene complexes in ethylene polymerizationстатья
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Дата последнего поиска статьи во внешних источниках: 2 апреля 2015 г.
Аннотация:DFT study of magnesium dichloride effect on the catalytic activity of titanium complexes of the composition LTi(Y)Cl (1) (where L is the saligenin type ligand and Y = Cl or CH3) in olefin polymerization reactions has demonstrated that heterobinuclear Ti and Mg compound 2 with –O– and –Cl– bridging bonds is the most stable product of the reaction of MgCl2 molecule with complex 1 and the most probable catalytic particle for ethylene polymerization reaction.