Thermodynamic functions of buthylderivatives of ferroceneстатья
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Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
Аннотация:The heat capacity of isobuthanoylferrocene, C(5)H(5)FeC(5)H(4)-COCH(CH(3))(2), was measured by low-temperature adiabatic calorimetry. The purity, temperature, and enthalpy of fusion were obtained. The ideal gas thermodynamic functions were derived at T = 298.15 K. The purity and thermodynamic functions of fusion of isobuthylferrocene, C(5)H(5)FeC(5)H(4)-CH(2)CH(CH(3))(2), were obtained by differential scanning calorimetry. The sample was synthesized by the reduction of isobuthanoylferrocene obtained by the direct acylation of ferrocene.