Electronic structure of carbynes studied by Auger and electron energy loss spectroscopyстатья
Информация о цитировании статьи получена из
Scopus,
Web of Science
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 28 января 2015 г.
Аннотация:The experimental carbon Auger lineshape for two samples of carbyne has been obtained. The electronic structure of carbynes has been calculated by the self-deconvolution of experimental Auger spectra. Results are discussed in terms of the electronic properties of linear molecules with 2–6 carbon atoms. It is shown that both carbyne samples have a linear structure with cumulene-type bonds but with different numbers of atoms in the chain. The influence of annealing at T < 600°C on the carbyne structure has been studied. The electron energy loss spectrum of carbynes is analyzed.