Supramolecular Complexes: Determination of Stability Constants on the Basis of Various Experimental Methodsстатья
Информация о цитировании статьи получена из
Web of Science,
Scopus
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 3 декабря 2017 г.
Аннотация:Stability constants and formation enthalpies of supramolecular complexes of crown ethers and
their cyclic and acyclic analogues are determined on the basis of experimental data obtained by different
physicochemical methods in the terms of a general approach developed and implemented in the ChemEqui
software package. The established regularities of variation of stability of complexes are discussed as dependent
on the ligand structure, nature of the cation, solvent, and anion. The applicability of the suggested method of
determining complexation selectivity is shown for multicomponent equilibria in solutions.