Pom complexes with noble metals: New insights into synthesis and reactivityкнига
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Авторы:
Sokolov M.N.,
Adonin S.A.,
Vicent C.
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Год издания:
2015
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Место издания:
Nova Science Publishers, Inc
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Аннотация:
Noble metal-containing polyoxometalates (POM) represent a rapidly depeloping area. These complexes are important for catalytic water splitting and transformations of various organic substrates. Moreover, incorporation of noble metals into POM offers new structural and electronic features for the coordination environment of a noble metal ion. This incorporation also supports strong metal-metal bonding, provides unique stereochemistry around noble metal ion, allows subtle chemical softness/hardness interplay, and leads to enhanced stability of organometallic derivatives.This contribution reports new results in the field of coordination chemistry of Rh, Ir, Ru, Pt and Au with homo- and heteropolytungstates. В© 2015 Nova Science Publishers, Inc.
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Добавил в систему:
Адонин Сергей Александрович