ИСТИНА

This report describes the whole pallette of the supramolecular interations, including the coordination bonds (CB), hydrogen bonds (HB), halogen bonds (HalB), halogen…pi interactions (HalPi), C-H…Pi interactions (CHPi), pi-pi stacking interactions (PiPi), and some other less energetic but nontheless important types of intermolecular bonds, which could be found in the solid state and gel state chemistry. All the examples are illustrated by the author's works on 3,7-diazabicyclo[3.3.1]nonanes (aka bispidines) and their structural analogues (Scheme). This work was supported by ZIOC RAS. References [1] Shcherbakov, D.; Baev, D.; Kalinin, M.; Dalinger, A.;Chirkova, V.; Belenkaya, S.; Khvostov, A.; Krut’ko, D.; Medved’ko, A.; Volosnikova, E.; Sharlaeva, E.; Shanshin, D.; Tolstikova, T.; Yarovaya, O.; Maksyutov, R.; Salakhutdinov, N.; Vatsadze, S. ACS Med Chem Lett, 2021 https://doi.org/10.1021/acsmedchemlett.1c00299. [2] Churakov, A.V.; Medved’ko, A. V.; Prikhodchenko, P. V.; Krut’ko, D. P.; Vatsadze, S. Z. Mend Comm, 2021, 31, 352 https://doi.org/10.1016/j.mencom.2021.04.023. [3] Mezentsev-Cherkes, I. A.; Shestimerova, T. A.; Medved'ko, A. V.; Kalinin, M. A.; Kuznetsov, A. N.; Wei, Zh.; Dikarev, E. V.; Vatsadze, S. Z.; Shevelkov A. V. Cryst Eng Comm 2021 https://doi.org/10.1039/D0CE01730B. [4] Dalinger, A. I.; Medved’ko, A. V.; Kalinin, M. A.; Sereda, V. A.; Churakov, A. V.; Vatsadze, S. Z. Russ Chem Bull, 2021, 70, 1002 https://doi.org/10.1007/s11172-021-3180-9. [5] Medved'ko, A. V.; Krut'ko, D. P.; Gaisen, S. V.; Churakov, A. V.; Minyaev, M. E.; Moiseeva, A. A.; Lemenovsky, D. A.; Yu, H.; Wang, L.; Vatsadze, S. Z. J Organomet Chem, 2021, 949, 121945 https://doi.org/10.1016/j.jorganchem.2021.121945. [6] Vatsadze, S. Z.; Medved’ko, A. V.; Bodunov, A. A.; Lyssenko, K. A. Mend Comm, 2020, 30, 344 https://doi.org/10.1016/j.mencom.2020.05.028 [7] Medved'ko, A.; Dalinger, A.; Niruev, V.; Ezhov, A.; Churakov, A.; Howard, J. A. K.; Shiryaev, A.; Baranchikov, A.; Ivanov, V.; Vatsadze, S. Nanomaterials, 2019, 9, 89 https://doi.org/10.3390/nano9010089. [8] Vatsadze, S. Z.; Manaenkova, M. A.; Vasilev, E. V.; Venskovsky, N. U.; Khrustalev, V. N. Acta Cryst E, 2017, 73, 1097 https://doi.org/10.1107/S2056989017009458. [9] Vatsadze, S. Z.; Shulga, D. A.; Loginova, Y. D.; Vatsadze, I. A.; Wang, L.; Yu, H.; Kudryavtsev, K. V. Mend Comm, 2016, 26, 212 https://doi.org/10.1016/j.mencom.2016.04.011. [10] Medved’ko, A. V.; Egorova, B. V.; Komarova, A. A.; Rakhimov, R. D.; Krut’ko, D. P.; Kalmykov, S. N.; Vatsadze, S. Z. ACS Omega, 2019, 1, 854 https://doi.org/10.1021/acsomega.6b00237. [11] Vatsadze, S. Z.; Semashko, V. S.; Manaenkova, M. A.; Krut'ko, D. P.; Nuriev, V. N.; Rakhimov, R. D.; Davlyatshin, D. I.,; Churakov, A. V.; Howard, J. A. K.; Maksimov, A. L.; Wang, L.; Yu, H. Russ Chem Bull, 2014, 63, 895 https://doi.org/10.1007/s11172-014-0526-6. [12] Kudryavtsev, K. V.; Shulga, D. A.; Chupakhin, V. I.; Sinauridze, E. I.; Ataullakhanov, F. I.; Vatsadze, S. Z. Tetrahedron, 2014, 70, 7854 https://doi.org/10.1016/j.tet.2014.09.009.