Synthesis and study of ruthenium phthalocyanine complexesстатья
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Дата последнего поиска статьи во внешних источниках: 18 июля 2013 г.
Аннотация: Methods of synthesis of ruthenium tetra-tert-butylphthalocyaninate ((PcRu)-Ru-t) were developed. The synthesis performed in both autoclave and in open system (in isoamyl alcohol in the presence (1,8-diazabicyclo[5,4,0]undecene) resulted in PctRu(CO) containing CO as axial ligand. When quinoline was used in the synthesis of (PcRu)-Ru-t, the (PuRu)-Ru-t(Iqnl)(2) complex was obtained with two isoquinoline molecules (Iqnl) as axial ligands, which were detached consecutively in the course of thermogravimetric analysis. The compounds formed were studied by different physicochemical methods: electron, IR, and H-1 NMR spectroscopies, MALDI-TOF mass spectroscopy, thermoggravimetric and elemental analyses.