Аннотация:We report the results of 57Fe Mössbauer studies on perovskite-like cobaltites-ferrites ScCo1-xFexO3 (x = 0.05, 0.4), where the partial "inversion" of the positions of cations with similar size A3+ (= Sc) and M3+ (= Fe, Co) is possible. It was shown that 57Fe3+ ions occupy two crystallographic positions corresponding to the A and B sublattices of ABO3 perovskite.